Analytical Chemistry Question 53

Question: Which one of the following can be used in place of $ NH_4Cl $ for the identification of the third group radicals-

Options:

A) $ NH_4NO_3 $

B) $ {{(NH_4)}_2}SO_4 $

C) $ {{(NH_4)}_2}CO_3 $

D) $ NaCl $

Show Answer

Answer:

Correct Answer: A

Solution:

[a] As it provides $ N{H^{+}}_4 $ ions which suppresses the ionization of $ NH_4OH $ so that only the group III cations are precipitated as hydroxides because of their low solubility products and $ N{O^{-}}_3 $ ions do not produce precipitate with the cations of IVth, Vth and VIth groups.