Analytical Chemistry Question 54

Reagent used in the qualitative analysis of Group IV is

Options:

A) $ HCl $

B) $ H_2S $ (acidic)

C) $ {{(NH_4)}_2}S $

D) None of these

Show Answer

Answer:

Correct Answer: B

Solution:

In presence of NH4OH, dissociation of H2S is remarkably high so increases the solubility product of IVth group sulphides $ H_2S $

$ 2{H^{+}}+{S^{2-}} $

$ NH_4OH\to NH_4^{+}+O{H^{-}} $

$ O{H^{-}}\ +\ {H^{+}}\ \to \ H_2O $



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