Analytical Chemistry Question 61

Question: Distinguishing reagent between silver and lead salts is

[MADT Bihar 1984]

Options:

A) $ H_2S $ gas

B) Hot dilute $ HCl $ solution

C) $ NH_4Cl $ (solid) + $ NH_4OH $ solution

D) $ NH_4Cl $ (solid) + $ {{( NH_4 )}_2}CO_3 $ solution

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Answer:

Correct Answer: B

Solution:

Both $ Pb $ and $ Ag $ form white ppt. of their chlorides. But $ PbCl_2 $ is soluble in hot water while $ AgCl $ does not dissolve in hot water.