Analytical Chemistry Question 82

Question: Which of the following gives a ppt. with $ Pb{{( NO_3 )}_2} $ but not with $ Ba{{( NO_3 )}_2} $

[CPMT 1979; MP PET 1997]

Options:

A) $ NaCl $

B) Sodium acetate

C) Sodium nitrate

D) Sodium hydrogen phosphate

Show Answer

Answer:

Correct Answer: A

Solution:

As $ Pb{{( NO_3 )}_2} $ is an ionic compound so the reaction is easy. $ Pb{{( NO_3 )}_2}+~2NaCl $

$ \to \ 2NaNO_3\ +\ PbCl_2 $ , but $ Ba{{( NO_3 )}_2} $ has a higher lattice energy, so no reaction takes place.