Analytical Chemistry Question 87

Question: When $ HCl $ gas is passed through saturated solution of $ BaCl_2 $ , a white ppt. is obtained. This is due to

[CPMT 1979]

Options:

A) Impurities in $ BaCl_2 $

B) Impurities in $ HCl $

C) Precipitation of $ BaCl_2 $

D) Formation of complex

Show Answer

Answer:

Correct Answer: C

Solution:

White precipitate obtained is of $ BaCl_2 $ , as the $ C{l^{-}} $ ion’s concentration increases due to the addition of HCl, the ionic product becomes more than solubility product and thus, BaCl2 is precipitated