Analytical Chemistry Question 98

Question: Nessler’s reagent is used to detect

[CPMT 1989; AIIMS 1997; MP PET 1999]

Options:

A) $ CrO_4^{2-} $

B) $ PO_4^{3-} $

C) $ MnO_4^{-} $

D) $ NH_4^{+} $

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Answer:

Correct Answer: D

Solution:

Nessler’s reagent gives red precipitate with $ NH_4^{+} $

$ NH_4Cl+2K_2[HgI_4]+4KOH\to $

$ \underset{\text{Iodide of Millon }’\text{ s base (Brown ppt)}}{\mathop{NH_2-Hg-O-Hg-I}}+\ 7KI\ +\ KCl\ +\ 3H_2O $