Biomolecules Question 187

Question: Which of the following pairs can be distinguished by Fehling’s solution-

Options:

A) Glucose and fructose

B) Glucose and sucrose

C) Methanal and ethanol

D) Hydroxypropanone and benzaldehyde.

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Glucose is a hemiacetal, so in presence of a base (alkaline medium is provided by Fehling’s solution) it can develop -CHO group in the form of open chain structure which responds Fehling’s solution. Sucrose is a glycoside (acetal), i.e. its hemiacetal OH groups (one due to glucose and another due to fructose) are not free, so it can’t attain -CHO group. Hence it will not respond Fehling’s solution.