Biomolecules Question 203

Question: What will happen when D-(+)-glucose is treated with methanolic $ -HCl $ followed by Tollens’ reagent-

Options:

A) A black ppt. will be formed

B) A red ppt. will be formed

C) A green colour will appear

D) No characteristic colour or ppt. will be formed.

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Answer:

Correct Answer: D

Solution:

[d] Reaction of D-(+)-glucose with methanolic $ HCl $ leads to formation of methyl glucoside ( $ C_1-OH $ group is methylated) which, being acetal, is not hydrolysable by base, so it will not respond Tollen’s reagent.