Carboxylic Acids Question 122

Question: $ CH_3COOH $ is reacted with $ CH\equiv CH $ in presence of $ H{g^{++}}, $ the product is

[DPMT 2004; BHU 1998]

Options:

A) $ \underset{\underset{CH_2(OOCH_3)}{\mathop{|}}}{\mathop{CH_3(OOCCH_3)}} $

B) $ \underset{\begin{smallmatrix} | \\ CH_2-(OOC-CH_3) \end{smallmatrix}}{\mathop{CH_3}} $

C) $ \underset{\begin{smallmatrix} | \\ CH{{(OOC-CH_3)}_2} \end{smallmatrix}}{\mathop{CH_3}} $

D) None of these

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Answer:

Correct Answer: C

Solution:

$ CH\equiv CH+CH_3COOH\xrightarrow{[H{g^{2+}}]} $

$ \underset{Vinylacetate}{\mathop{H_2C=CH-OCOCH_3}}\xrightarrow{CH_3COOH} $

$ \underset{Ethylideneacetate}{\mathop{CH_3-CH{{(O-COCH_3)}_2}}} $ This reaction is an example of addition reaction.