Carboxylic Acids Question 145

Question: In the presence of iodine catalyst, chlorine reacts with acetic acid to form

[MP PMT 1997]

Options:

A) $ \overset{\overset{O}{\mathop{||}}}{\mathop{CH_3-C-Cl}} $

B) $ \overset{\overset{O}{\mathop{||}}}{\mathop{CH_2Cl-C-OH}} $

C) $ \overset{\overset{Cl}{\mathop{|}}}{\mathop{\underset{\underset{Cl}{\mathop{|}}}{\mathop{CH_3-C-OH}}}} $

D) $ \overset{\overset{O}{\mathop{||}}}{\mathop{CH_3-C-O-Cl}} $

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Answer:

Correct Answer: B

Solution:

$ CH_3COOH\xrightarrow{I_2/Redp}CH_2Cl-COOH $