Carboxylic Acids Question 157

Question: An organic compound of molecular formula $ C_4H _{10}O $ does not react with sodium. With excess of $ HI, $ it gives only one type of alkyl halide. The compound is

[SCRA 2001]

Options:

A) Ethoxyethane

B) 2-Methoxypropane

C) 1-Methoxypropane

D) 1-Butanol

Show Answer

Answer:

Correct Answer: A

Solution:

Since a single alkyl halide is formed on treatment with HI, it must be a symmetrical ether i.e., ethoxyethane. $ C_2H_5OC_2H_5+2HI\to 2C_2H_5I+H_2O $