Carboxylic Acids Question 33

Question: Ethyl acetate is obtained when methyl magnesium iodide reacts with

[Tamil Nadu CET 2002]

Options:

A) Ethyl formate

B) Ethyl chloroformate

C) Acetyl chloride

D) Carbon dioxide

Show Answer

Answer:

Correct Answer: B

Solution:

$ CH_3MgI+\underset{Ethylchloroformate}{\mathop{Cl-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-OC_2H_5}}\to $

$ [ Cl-\underset{CH_3}{\overset{OMgI}{\mathop{\underset{|}{\overset{|}{\mathop{C-OC_2H_5}}}}}} ] $

$ \to \underset{Ethylacetate}{\mathop{CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-OC_2H_5}}+Mg<\begin{matrix} Br \\ I \\ \end{matrix} $