Carboxylic Acids Question 39

Question: Which reaction is used for the preparation of $ \alpha - $ Bromoacetic acid-

[MP PET 2004; MP PET/PMT 1998]

Options:

A) Kolbe’s Reaction

B) Reimer-Tiemann Reaction

C) Hell volhard Zelinsky Reaction

D) Perkin’s Reation

Show Answer

Answer:

Correct Answer: C

Solution:

When $ Cl_2 $ or $ Br_2 $ is react with carboxylic acid in the presence of red phosphorus then a-hydrogen of carboxylic acid is replaced by $ Cl_2 $ or $ Br_2 $

$ \underset{Aceticacid}{\mathop{CH_3COOH}}\xrightarrow{Br_2}\underset{\alpha -bromoaceticacid}{\mathop{CH_2BrCOOH}} $ This reaction is known as Hell Volhard Zelinsky reaction.