Carboxylic Acids Question 43

Question: In the reaction, $ C_6H_5OH\xrightarrow{NaOH}(A) $ $ \underset{140{}^\circ C,\ (4-7atm)}{\mathop{\xrightarrow{\ CO_2\ \ \ \ \ \ \ \ \ \ \ \ }}}(B) $ $ \xrightarrow{HCl}(C), $ the compound is

[Pb. CET 2001]

Options:

A) Benzoic acid

B) Salicylaldehyde

C) Chlorobenzene

D) Salicylic acid

Show Answer

Answer:

Correct Answer: D

Solution:

Treatment of sodium salt of phenol with $ CO_2 $ under pressure bring about substitution of the carbonyl group $ -COOH, $ for the hydrogen of the ring. This is called as Kolbe’s reaction