Carboxylic Acids Question 47

Question: $ CH_3CONH_2\xrightarrow{NaNO_2/HCl}X $

[Pb. CET 2003]

Options:

A) $ CH_3COOH $

B) $ CH_3CO\overset{+}{\mathop{N}}H_3C{l^{-}} $

C) $ CH_3NH_2 $

D) $ CH_3CHO $

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Answer:

Correct Answer: A

Solution:

Amide, on treating with $ HNO_2, $ give acids. $ CH_3CONH_2\underset{(HNO_2)}{\mathop{\xrightarrow{NaNO_2/HCl}}}\underset{aceticacid}{\mathop{CH_3COOH}}+N_2+H_2O $