Carboxylic Acids Question 5

Question: The most acidic of the following is

[J & K 2005]

Options:

A) $ ClCH_2COOH $

B) $ C_6H_5COOH $

C) $ CD_3COOH $

D) $ CH_3CH_2COOH $

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Answer:

Correct Answer: A

Solution:

Any electron withdrawing substituent (having-I-effect) stabilises the anion by dispersing the negative charge and therefore, increases the acidity. Chlorine is an electron withdrawing group.