Chemical Bonding And Molecular Structure Question 17

Question: The covalency of nitrogen in $ HNO_3 $ is [CPMT 1987]

Options:

A) 0

B) 3

C) 4

D) 5

Show Answer

Answer:

Correct Answer: C

Solution:

Let’s approach this step-by-step:

  1. First, let’s recall what covalency means: Covalency is the number of electron pairs that an atom shares with other atoms in a molecule.

  2. Now, let’s look at the structure of HNO₃ (Nitric Acid):

    H-O
    N=O // O

  3. Let’s count the bonds that nitrogen forms:

    • Single bond with one oxygen (H-O-N)
    • Double bond with one oxygen (N=O)
    • Single bond with another oxygen, which then forms a double bond with that oxygen (N-O=O)
  4. Counting these bonds:

    • 1 for the single bond with O
    • 2 for the double bond with O
    • 1 for the single bond in N-O=O

    Total: 1 + 2 + 1 = 4

  5. Each of these bonds represents a shared electron pair.

Therefore, the covalency of nitrogen in HNO₃ is 4.

The correct answer is C) 4.