Chemical Thermodynamics Question 207

Question: For the reaction taking place at certain temperature $ NH_2COONH_4(s)\leftrightharpoons 2NH_3(g)+CO_2(g), $ if equilibrium pressure is 3X bar then $ \Delta _rG{}^\circ $ would be

Options:

A) $ -RT $ \ln $ 9-3RT $ \ln X

B) RT ln(4-3RT) ln X

C) $ -3RT $ ln X

D) None of these

Show Answer

Answer:

Correct Answer: D

Solution:

$ \Delta {{G}^{{}^\circ }}=-RT $ ln $ K_{p};K_{p}={{( 2x )}^{2}}(1-x)=4x^{3}(1-x) $

$ \Delta G{}^\circ =-RT \ln(4X^{3}) $

$ \Delta G{}^\circ =-RT \ln K $ In $ 4-3RT $ In X



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