Chemical Thermodynamics Question 456

Question: The equilibrium concentration of the species in the reaction $ A+B= C+D $ are 3, 5, 10 and 15 $ mole {{L}^{-1}} $ respectively at $ 300 K $ the $ \Delta G $ for the reaction is [Pb. PMT 2004]

Options:

A) 13.81

B) - 1381.8

C) - 138.18

D) 1391.6

Show Answer

Answer:

Correct Answer: B

Solution:

$ \Delta G=-2.303 RT \log {K}’ $ , Here $ R=2 cal,T=300K $

$ {K}’=\frac{10\times 15}{3\times 5}=10 $ ; $ \Delta G=-2.303\times 2\times 300\times {\log_{10}}10 $

$ =-2.303\times 2\times 300\times 1=-1381.8 cal $