Classification Of Elements And Periodicity In Properties Question 3

Question: The incorrect statement among the following is [IIT-JEE 1997]

Options:

A) The first ionisation potential of $ Al $ is less than the first ionisation potential of $ Mg $

B) The second ionisation potential of $ Mg $ is greater than the second ionisation potential of $ Na $

C) The first ionisation potential of $ Na $ is less than the first ionisation potential of $ Mg $

D) The third ionisation potential of $ Mg $ is greater than the third ionisation potential of $ Al $

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Answer:

Correct Answer: B

Solution:

I.E.(II) of $ Na $ is higher than that of $ Mg $ because in case of $ Na $ , the second $ {{e}^{-}} $ has to be remove from the noble gas core while in case of $ Mg $ removal of second $ {{e}^{-}} $ gives a noble gas core. $ Mg $ has high first ionisation potential than $ Na $ because of its stable $ ns^{2} $ configuration.