Co Ordination Compounds Question 114

Question: In the complexes $ {{[Fe{{(H_2O)}_6}]}^{3+}},{{[Fe{{(CN)}_6}]}^{3-}} $ , $ {{[ Fe{{( C_2O_4 )}_3} ]}^{3-}} $ and $ {{[FeCl_6]}^{3-}} $ , more stability is shown by

Options:

A) $ {{[Fe{{(H_2O)}_6}]}^{3+}} $

B) $ {{[Fe{{(CN)}_6}]}^{3-}} $

C) $ {{[Fe{{(C_2O_4)}_3}]}^{3-}} $

D) $ {{[FeCl_6]}^{3-}} $

Show Answer

Answer:

Correct Answer: C

Solution:

$ {{[ Fe{{( C_2O_4 )}_3} ]}^{3-}} $ .

The iron is present in the highest oxidation state $ F{e^{3+}} $ and $ C_2O{{_4^{2-}}^{~}} $ is a chelating ligand.

Chelates are always form more stable complexes



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