Co Ordination Compounds Question 118

Question: Which of the following paramagnetic ions would exhibit a magnetic moment (spin only) of the order of 5 BM? (At. Nos. Mn = 25, Cr = 24, V = 23, Ti =22)

Options:

A) $ M{n^{2+}} $

B) $ T{i^{2+}} $

C) $ {V^{2+}} $

D) $ C{r^{2+}} $

Show Answer

Answer:

Correct Answer: D

Solution:

Ion Electronic Configuration Magnetic moment $ ( \sqrt{n(n+2)} ) $
$ C{r^{2+}} $ $ d^{4} $ $ \sqrt{4(4+2)}=4.9 $
$ M{n^{2+}} $ $ d^{5} $ $ \sqrt{5(5+2)}=5.8 $
$ T{i^{2+}} $ $ d^{2} $ $ \sqrt{2(2+2)}=2.4 $
$ {V^{2+}} $ $ d^{3} $ $ \sqrt{3(3+2)}=3.8 $

Hence $ C{r^{2+}} $ has magnetic moment of the order of 5 B.M.



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