Co Ordination Compounds Question 126

Question: $ [Cr{{(H_2O)}_6}]Cl_3 $ (atomic number of $ Cr=24 $ ) has a magnetic moment of 3.83 BM. The correct distribution of 3d-elections in the chromium present in the complex is

Options:

A) $ 3d_xy^{1},3d_yz^{1},3d_zx^{1} $

B) $ 3d_xy^{1},3d_yz^{1},3d_{z^{2}}^{1} $

C) $ 3d_{(x^{2}-y^{2})}^{1},3d_{z^{2}}^{1},3d_zx^{1} $

D) $ 3d_xy^{1},3d_{(x^{2}-y^{2})}^{1},3d_xz^{1} $

Show Answer

Answer:

Correct Answer: A

Solution:

Magnetic moment indicates that there are three unpaired electrons present in chromium.

These must be present in lower energy orbitals which are $ 3d_{xy},3d_{yz} $ and $ 3d_{xz} $ .



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