Co Ordination Compounds Question 150

Question: Which of the following statements is correct for the complex $ Ca_2[Fe{{(CN)}_5}O_2] $ having $ t_2g^{6},e_g^{0} $ electronic configuration?

Options:

A) $ d^{2}sp^{3} $ hybridised and diamagnetic

B) $ sp^{3}d^{2} $ hybridised and paramagnetic

C) $ sp^{3}d^{2} $ hybridised and diamagnetic

D) $ d^{2}sp^{3} $ hybridised and paramagnetic

Show Answer

Answer:

Correct Answer: D

Solution:

$ F{e^{2+}}: $ Complex is paramagnetic due to presence of unpaired electron at $ O_2^{-} $ i.e., superoxide acting as ligand.



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