Co Ordination Compounds Question 182

Question: Which of the following complexes has the highest stability constant at 298 K

Options:

A) $ {{[ CdCl_4 ]}^{2-}} $

B) $ {{[ CdBr_4 ]}^{2-}} $

C) $ {{[ CdI_4 ]}^{2-}} $

D) $ {{[ Cd{{( CN )}_4} ]}^{2-}} $

Show Answer

Answer:

Correct Answer: D

Solution:

The cyano and ammine complexes are far more stable than those formed by halide ions.

This is due to the fact that $ NH_3 $ and $ C{N^{-}} $ are strong lewis bases.



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