Co Ordination Compounds Question 211

Question: Which of the following statements is incorrect?

[KCET 2004]

Options:

A) In $ K_3[Fe{{(CN)}_6}], $ the ligand has satisfied only the secondary valency of ferric ion.

B) In $ K_3[Fe{{(CN)}_6}], $ the ligand has satisfied both primary and secondary valencies of ferric ion.

C) In $ K_4[Fe{{(CN)}_6}], $ the ligand has satisfied both primary and secondary valencies of ferrous ion.

D) In $ [Cu{{(NH_3)}_4}]SO_4, $ the ligand has satisfied only the secondary valency of copper.

Show Answer

Answer:

Correct Answer: A

Solution:

In $ K_3[Fe{{(CN)}_6}] $ the ligand are negative which is present in coordination spheres shows a dual behaviour.

It may satisfied both primary & secondary valencies while neutral ligand satisfied only secondary valencies.



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