Co Ordination Compounds Question 277

Question: In Fe $ {{(CO)}_5} $ , the Fe $ - $ C bond possesses:

Options:

A) $ \pi $ -character only

B) Both $ \sigma $ and $ \pi $ characters

C) Ionic character

D) $ \sigma $ -character only

Show Answer

Answer:

Correct Answer: B

Solution:

Due to some back bonding by sidewise overlapping between d-orbitals of metal and p-orbital of carbon, the Fe-C bond in $ Fe{{(CO)}_5} $ has both $ \sigma $ and $ \pi $ characters.



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