Co Ordination Compounds Question 289

Question: Which of the following statements is not true?

Options:

A) $ {{[MnCl_4]}^{2-}} $ ion has tetrahedral geometry and paramagnetic.

B) $ {{[Mn{{(Cl)}_6}]}^{2-}} $ ion has octahedral geometry and paramagnetic.

C) $ {{[Cu{{(CN)}_4}]}^{3-}} $ - has square planar geometry and diamagnetic.

D) $ [Ni{{(Ph_3P)}_2}Br_3] $ has trigonal bipyramidal geometry 2 is paramagnetic.

Show Answer

Answer:

Correct Answer: C

Solution:

Metal atom/ion Configuration Geometry Magnetic nature $ Mn $

$ {{[MnCl_4]}^{2-}} $ Tetrahedral Paramagnetic

$ {{[MnCl_6]}^{4-}} $ Octahedral Paramagnetic

$ {{[Cu{{(CN)}_4}]}^{3-}} $ Tetrahedral Diamagnetic

$ [Ni{{(Ph_3P)}_2}Br_3] $ (Bulkier gp.) Tetrahedral Paramagnetic



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