Co Ordination Compounds Question 55

Question: Coordination number of Cr is six. A complex with $ C_2O_4^{2-} $ , en and superoxide $ O_2^{-} $ will be in the ratio to make complex $ {{[Cr{{(C_2O_4)} _{x}},{{(en)} _{y}}{{(O_2)} _{z}}]}^{-}} $

Options:

A) x-1 y-1 z-1

B) x-1 y-1 z-2

C) x-1 y-2 z-2

D) x-2 y-1 z-1

Show Answer

Answer:

Correct Answer: D

Solution:

$ C{r^{3+}},C_2O_4^{2-},{{(en)}^{0}},O_2 $

$ C_2O_4^{2-} $ and $ {{( en )}^{0}} $ are bidentate ligands.

CN of $ Cr^{3+} $=6,

Oxalate and en are bidentate ligands.



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