Co Ordination Compounds Question 66

Question: An aqueous solution of titanium chloride, when subjected to magnetic measurement, measured zero magnetic moment. Assuming the octahedral complex in aqueous solution, the formulae of the complex is:

Options:

A) $ [ Ti{{( H_2O )}_6} ]Cl_2 $

B) $ [ Ti{{( H_2O )}_6} ]Cl_4 $

C) $ [ TiCl_3{{( H_2O )}_3} ] $

D) $ [ TiCl_2{{( H_2O )}_4} ] $

Show Answer

Answer:

Correct Answer: B

Solution:

$ [ Ti{{( H_2O )}_6} ]Cl_4 $ Coordination number $ 6\Rightarrow $ octahedral complex Ti is in +4 oxidations state
$ \Rightarrow $ no unpaired electrons
$ \Rightarrow $ magnetic moment = 0 B.M.



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