D And F Block Elements Question 308

Question: $ MnO_4^{-} $ is of intense pink colour, though Mn is in (+7) oxidation state. It is due to

Options:

A) oxygen gives colour to it

B) charge transfer when Mn gives its electron to oxygen

C) charge transfer when oxygen gives its electron to mb making it Mn(+VI) hence coloured

D) none is correct

Show Answer

Answer:

Correct Answer: C

Solution:

The intense pink colour of $ MnO_4^{-} $ is not due to d-d transition but due to charge transfer (from O to Mn) reducing the oxidation state of Mn form +6 to +5 momentarily.



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