D And F Block Elements Question 337

Which of the following statements is correct about equivalent weight of $ KMnO_4 $ in acidic medium

[MP PET 1994]

Options:

A) It has one third of its molecular weight in alkaline medium

B) It has a molecular weight that is one fifth in an alkaline medium

C) It is equal to its molecular weight in an acidic medium

D) It is one third of its molecular weight in an acidic medium

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Answer:

Correct Answer: A

Solution:

It is one third of its molecular weight in alkaline medium because it releases 3 nascent oxygen atoms in alkaline medium.

$ 2KMnO_4+H_2O,\xrightarrow{+3{{e}^{-}}},2KOH+2MnO_2+3[O] $ \ Equivalent weight = $ \frac{M}{5} $



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