Equilibrium Question 344

What is the $ pH $ of $ Ba{{(OH)}_2} $ if normality is 0.1 [CPMT 1996]

Options:

4

10

7

9

Show Answer

Answer:

Correct Answer: B

Solution:

$ Ba{{(OH)}_2} $ ⇌ $ Ba^{2+} + 2OH^{-} $

One molecule on dissociation furnishes $ 2OH^{-} $ ions. So, $ [OH^{-}]=2\times {10^{-4}}M $

$ N=M\times 2 $ ; $ M=\frac{N}{2}=\frac{2\times {10^{-4}}}{2}={10^{-4}} $ pOH $ =-\log [O{H^{-}}]=-\log (1\times {10^{-4}})=-4 $

$ pH+pOH=14 $ ; $ pH=14-4=10 $ .



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