Equilibrium Question 37

In the reaction: $ H_2S $ ⇄ $ 2{H^{+}}+{S^{2-}} $ , when $ NH_4OH $ is added, then [KCET (Med.) 1999; AFMC 2000]

Options:

A) $ {S^{2-}} $ is precipitate

B) No action takes place

C) Concentration of $ {S^{2-}} $ decreases

D) Concentration of $ {S^{2-}} $ increases

Show Answer

Answer:

Correct Answer: D

Solution:

In IVth group the $ {S^{2-}} $ concentration increases when added the $ NH_4OH $ because

$ NH_4OH $ ⇌ $ NH_4^{+}+O{H^{-}} $

$ H_2S $ ⇌ $ 2{H^{+}}+{S^{2-}} $

$ OH^{-}+{H^{+}} $ ⇌ $ H_2O $ . So that $ {S^{2-}} $ is increased.



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