Equilibrium Question 750

Question: Assuming that the degree of hydrolysis is small, the pH of 0.1 M solution of sodium acetate $ (K_{a}=1.0\times {10^{-5}}) $ will be:

Options:

5.0

6.0

8.0

9.0

Show Answer

Answer:

Correct Answer: D

Solution:

Sodium acetate is a salt of weak acid and strong base. $ \therefore pH=7+\frac{1}{2}pK_{a}=\frac{1}{2}\log c $ where $ pK_{a}=-\log K_{a}=-\log{10^{-5}}=5 $

$ logc=log{10^{-1}}=-1 $

$ pH=7+\frac{5}{2}-\frac{1}{2}=8.0 $



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