Hydrocarbons Question 102

Question: Which of the following does not give alkane [MP PMT 1999]

Options:

A) Reaction of $ CH_3I $ with Na in ether

B) Reaction of sodium acetate with sodalime

C) Electrolysis of concentrated sodium acetate solution

D) Reaction of ethyl chloride with alco. KOH

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Answer:

Correct Answer: D

Solution:

$ CH_3-CH_2-Cl+\underset{\text{(alc}\text{.)}}{\mathop{KOH}}\to \underset{Ethene}{\mathop{CH_2=CH_2}}+KCl+H_2O $ In presence of alc.

KOH dehydrohalogenation occur and alkene is formed.