Hydrocarbons Question 146

Question: In which of the following, addition of $ HBr $ does not take place against Markownikoff’s rule or Anti-Markownikoff addition of $ HBr $ is not observed for [IIT-JEE 1985; CBSE PMT 1994; MADT Bihar 1995; MP PMT 1999; AMU 2002]

Options:

A) Propene

B) But-1-ene

C) But-2-ene

D) Pent-2-ene

Show Answer

Answer:

Correct Answer: C

Solution:

$ CH_3-CH=CH-CH_3+HBr\xrightarrow{Peroxide} $

$ \underset{2-Bromobutane}{\begin{bmatrix} CH_3-CH_2-\underset{|}{\mathop{C}}H-CH_3 \\ Br \\ \end{bmatrix} } $

Anti-markownikoff’s rule is not applicable to symmetrical alkenes.