Hydrocarbons Question 151

Question: Which of the following would be least reactive towards bromine [NCERT 1981]

Options:

A) Nitrobenzene

B) Phenol

C) Anisole

D) Chlorobenzene

Show Answer

Answer:

Correct Answer: A

Solution:

Nitrobenzene is least reactive towards bromine because of presence of $ -NO_2 $ group decreases electron density at o and p positions and hence attack of electrophile on the benzene nucleus is difficult because + ve charge on o and p position repel the incoming electrophile.