Hydrocarbons Question 201

Question: Aqueous sulphuric acid reacts with 2-methyl-1-butene to give predominantly [Roorkee 1992]

Options:

A) Isobutyl hydrogen sulphate

B) 2-methyl-2-butanol

C) 2-methyl-1-butanol

D) Secondary butyl hydrogen sulphate

Show Answer

Answer:

Correct Answer: B

Solution:

$ \begin{matrix} CH_3 \\ C\underset{2-\text{methyl-1-butane}}{\mathop{H_2=\overset{|}{\mathop{C}}-CH_2-CH_3}}+H_2O\underset{\text{Markownikoff }’\text{ s rule}}{\mathop{\xrightarrow{H_2SO_4}}} \\ \end{matrix} $

$ \underset{2-\text{Methyl-2-butanol}}{\mathop{\begin{matrix} \ \ \ \ \ \ \ CH_3 \\ CH_3-\underset{|}{\overset{|}{\mathop{C}}}-CH_2-CH_3 \\ \ \ \ \ \ \ \ \ OH \\ \end{matrix} }} $