Hydrocarbons Question 21

Question: The major product formed when propene reacts with HBr in presence of peroxides is [NCERT 1980; CBSE PMT 1989]

Options:

A) n-propyl bromide

B) Isopropyl bromide

C) n-propyl alcohol

D) 1, 3-dibromopropane

Show Answer

Answer:

Correct Answer: A

Solution:

$ CH-CH=CH_2+HBr\xrightarrow{peroxide} $

$ \underset{n-propylbromide}{\mathop{CH_3-CH_2-CH_2-B}}r $

In presence of peroxide addition takes place according to Anti Markownikoff’s rule and hydrogen atom goes to that carbon atom which is less hydrogenated.