Hydrocarbons Question 233

Question: Identify the incorrect statement/statements:

(i) Alkynes are more reactive than alkenes towards electrophilic addition reaction (ii) Alkynes are less reactive than alkenes towards electrophilic addition reaction (iii) Alkynes decolourise $ Br_2 $ water (iv) Addition of HBr to alkynes in presence of peroxide proceeds via Markownikoff’s rule

Options:

A) (i) and (ii)

B) (ii) and (iii)

C) (i) and (iv)

D) (ii) and (iv)

Show Answer

Answer:

Correct Answer: C

Solution:

[c] More is the s-character more is its electrophilic nature out of alkenes and alkyne.

Thus alkynes are more reactive than alkenes towards nucleophilic reaction and reactive towards the electrophilic reaction.

Addition of $ HB _{r} $ in the presence of peroxide follows anti-markownikoff-’s Rule.