Hydrocarbons Question 278

Question: An unknown compound A has a molecular formula $ C_2H_6 $ , when A is treated with an excess of $ Br_2 $ , a new substance B with formula $ C_4H_6Br_2 $ is formed. A forms a white precipitate with ammonical silver nitrate solution. A may be

Options:

A) Butyne-1

B) Butyne-2

C) Butene-1

D) Butene-2

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Conversion of $ C_4H_6 $ to $ C_4H_6Br_2 $ indicates that the compound is either butyne-1 or butyne-2.

However, white precipitate with ammonical silver nitrate solution indicates that it is a terminal alkyne, i.e.

butyne-1 and not butyne-2