Hydrocarbons Question 291

Question: Which of the following compounds will form a hydrocarbon on reaction with Grignard reagent [CPMT 1988, 93]

Options:

A) $ CH_3CH_2OH $

B) $ CH_3CHO $

C) $ CH_3COCH_3 $

D) $ CH_3CO_2CH_2 $

Show Answer

Answer:

Correct Answer: A

Solution:

Compounds having active hydrogen $ ( ROH,H_2O,R-NH_2 ) $ can form alkane when treated with Grignard’s reagent $ CH_3CH_2OH+CH_3MgBr\to CH_4 $

$ +Mg<\begin{matrix} Br \\ OCH_2CH_3 \\ \end{matrix} $