Hydrocarbons Question 349

Question: Photochemical chlorination of alkane is initiated by a process of [Kerala PMT 2004]

Options:

A) Pyrolysis

B) Substitution

C) Cracking

D) Peroxidation

E) Homolysis

Show Answer

Answer:

Correct Answer: E

Solution:

Photochemical chlorination of alkane take place by free radical mechanism which are possible by Homolysis of C - C bond $ Cl_2\xrightarrow{hv}C{l^{\bullet }}+C{l^{\bullet }} $

$ CH_3-CH_3+C{l^{\bullet }}\to CH_3C{l^{\bullet }}+\dot{C}H_3 $