Hydrocarbons Question 396

Question: 2-Methylbutane on reacting with bromine in the presence of sunlight gives mainly [AIEEE 2005]

Options:

A) 1-bromo-2-methylbutane

B) 2-bromo-2-methylbutane

C) 2-bromo-3-methylbutane

D) 1-bromo-3-methylbutane

Show Answer

Answer:

Correct Answer: B

Solution:

$ H_3C-\underset{CH_3}{\mathop{\underset{|}{\mathop{CH-}}}}CH_2-CH_3+Br_2\xrightarrow{{}} $

$ \underset{Major}{\mathop{\begin{matrix} Br \\ | \\ H_3C-C-CH_2 \\ | \\ CH_3 \\ \end{matrix}-CH_3}} $