Hydrocarbons Question 49

Question: The only alcohol that can be prepared by the indirect hydration of alkene is [AFMC 2005]

Options:

A) Ethyl alcohol

B) Propyl alcohol

C) Isobutyl alcohol

D) Methyl alcohol

Show Answer

Answer:

Correct Answer: A

Solution:

$ \underset{CH_2}{\overset{CH_2}{\mathop{||}}}+H_2SO_4\to \underset{CH_2HSO_4}{\overset{CH_3}{\mathop{|}}}\xrightarrow{H_2O} $

$ \underset{CH_2OH}{\overset{CH_3}{\mathop{|}}}+H_2SO_4 $ Except ethyl alcohol, no other primary alcohol can be prepared by this method as the addition of $ H_2SO_4 $ follows Markownikoff’s rule.

Generally secondary and tertiary alcohols are obtained.