Hydrocarbons Question 90

Question: $ \begin{matrix} H_3C & {} & CH_3 \\ {} & >C=C< & {} \\ H_3C & {} & CH_3 \\ \end{matrix}\underset{KOH\text{(heat)}}{\mathop{\xrightarrow{X}}}\begin{matrix} CH_3 & {} & CH_3 \\ {} & >C=O+O=C< & {} \\ CH_3 & {} & CH_3 \\ \end{matrix} $ $ X $ in the above reaction is [CPMT 1985, 93]

Options:

A) $ HNO_3 $

B) $ O_2 $

C) $ O_3 $

D) $ KMnO_4 $

Show Answer

Answer:

Correct Answer: D

Solution:

$ \begin{matrix} CH_3 \\ CH_3 \\ \end{matrix}>C=C<\begin{matrix} CH_3 \\ CH_3 \\ \end{matrix}\underset{KOH(\text{heat)}}{\mathop{\xrightarrow{KMnO_4}}} $

$ \begin{matrix} CH_3 \\ \underset{Acetone}{\mathop{CH_3}} \\ \end{matrix}>C=O+O=C<\begin{matrix} CH_3 \\ \underset{Acetone}{\mathop{CH_3}} \\ \end{matrix} $