Hydrogen And Its Compounds Question 239

Question: A 5.0 mL solution of $ H_2O_2 $ liberates 1.27 g of iodine from an acidified KI solution. The percentage strength of $ H_2O_2 $ is

Options:

A) 11.2

B) 5.6

C) 1.7

D) 3.4

Show Answer

Answer:

Correct Answer: D

Solution:

[d] $ H_2O_2\equiv KI\equiv I_2 $

$ mEqofH_2O_2=5\times N $

$ mEqofI_2=\frac{Weight}{E.w}\times 1000 $

$ \frac{1.27}{127}\times 1000=10mEq $

$ I_2=M.w=254 $

$ E.w=\frac{M.w}{2}=\frac{254}{2}=127 $
$ \therefore mEqofH_2O_2=mEqofI_2 $

$ 5\times N=10 $
$ \therefore N=2 $ 1 N of $ H_2O_2=1/7 $ % of $ H_2O_2 $ 2 N of $ H_2O_2 $ = 3.4% $ H_2O_2 $