Organic Compounds Containing Halogens Question 109

Question: When ethyl amine is heated with chloroform and alcoholic KOH, a compound with offensive smell is obtained. This compound is

[CPMT 1983, 84; RPMT 2002]

Options:

A) A secondary amine

B) An isocyanide

C) A cyanide

D) An acid

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{ethylamineReaction}{\mathop{C_2H_5NH_2+CHCl_3}}+3KOH\to \underset{\text{(Unpleasant}\text{smell)}}{\mathop{\underset{Ethylisocyanide}{\mathop{C_2H_5N\vec{=}C}}}} $

$ +3KCl+3H_2O $