Organic Compounds Containing Halogens Question 123

Question: When chloroform is treated with conc. $ HNO_3 $ it gives

[CPMT 1986; MP PMT 1989; AFMC 1998, 99; EAMCET 1991; BHU 1999]

Options:

A) $ CHCl_2NO_2 $

B) $ CCl_3NO_2 $

C) $ CHCl_2HNO_3 $

D) None of these

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{Chloroform}{\mathop{CHCl_3}}+conc\text{. }HNO_3\to \underset{Chloropicrin}{\mathop{CCl_3-NO_2}}+H_2O $